The synthesis of the first two arylenealkyne conjugated macrocycles containing long alkylene bridge via Glaser coupling of template-directed tetraacetylenes was reported. 采用模板导向法高产率地合成了两个含长链亚烷基桥的芳炔类共轭大环。
Advances of Glaser Coupling Reaction Glaser偶联反应研究进展
This paper reviewed the recent advances of Glaser coupling reaction and its applications to the synthesis of conjugated polymers. The reaction mechanism was also discussed. 回顾了近年来Glaser偶联反应的研究进展,讨论了这一反应在共轭聚合物合成中的应用,并对其反应机理进行了探讨。
Blake's Misreading of Milton Advances of Glaser Coupling Reaction 布莱克对弥尔顿的误读Glaser偶联反应研究进展
Glaser coupling and Suzuki cross-coupling reaction are the most important methods in the construction of C-C bond compounds, and play a key role in the synthesis of natural products, drug synthesis, optoelectronic materials and many other areas. Glaser偶联反应和Suzuki交叉偶联反应都是构建C-C键的重要反应,在天然产物的合成、药物合成以及光电材料等诸多领域中有着非常重要的作用。
Compared to the reported copper-catalyzed system, the reactions did not require the protection of inert gases and no Glaser coupling side-products were detected, the catalyst is cheap, environmentally benign and reusable. 与已经报道的铜催化体系相比,该方法无需惰性气体保护,无Glaser偶联副反应发生,催化剂廉价高效、环境友好、可循环使用。
This paper gave an overview of the research process of the Glaser coupling and Suzuki cross-coupling in recent years, and developed new catalytic systems for the reactions. 本论文简要综述了近几年Glaser偶联和Suzuki偶联的研究进展。并在新的催化体系中对这些反应进行了研究和发展。